Charizard Pokmon Card: Prices, History & Why It's So Valuable Pokemon Mega Charizard X ex Ultra Premium Collection Released in 2014's Pokmon XY: Flashfire, this M Charizard EX #69 quickly became the chase card of the set. Collectors could only acquire it by pulling it from Flashfire booster packs, where Mega Mega Charizard X ex Phantasmal Flames (PFL) #13 Limitless An UNREAL find. The 1st Edition Base Set Shadowless Charizard is widely regarded as the most iconic and valuable Pokmon card ever printed. Released in early 1999 as part of the M Charizard EX Mega Battle Deck (TCG) Bulbapedia, the community driven Pokmon encyclopedia